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173 points rbanffy | 32 comments | | HN request time: 1.124s | source | bottom
1. VyseofArcadia ◴[] No.42127346[source]
Time scale is also something I want to know about. "Can I remove CO2 from the air and turn it into something valuable in a way that is cost effective?" is one question. Another question is, "Can I remove CO2 from the air and turn it into something valuable faster than a tree?"
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2. ben_w ◴[] No.42127397[source]
As this is more of "can we make carbon sequestering commercially viable, or at least less lossy", I'm less worried about that and would be more concerned about the global market for ethylene being "316.8 Million Tonnes in the year 2023"*, compared to the tens of gigatons of CO2 emissions — though on the plus side, I'm optimistic about removing most of those emissions and this kind of thing is still fine for the last 10%.

As for "less lossy" even if it's not always a commercial winner alone: my guess would be there's always going to be an easier way to get CO2 than "from the air", unless you're on Venus or Mars: take tree (or coal), cut up, put chips in oven, set on fire. Much higher CO2 concentration than air, likely to make most things that need CO2 much easier.

* https://finance.yahoo.com/news/global-ethylene-industry-repo...

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3. sampo ◴[] No.42127435[source]
> "Can I remove CO2 from the air and turn it into something valuable faster than a tree?"

In some climate zones, grasslands do it better than forests.

https://climatechange.ucdavis.edu/climate/news/grasslands-mo...

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4. not2b ◴[] No.42127671[source]
My guess is that it would be much more effective to capture and remove CO2 directly at the source, for example at a cement plant. While this could be done at a fossil fuel plant as well, it seems a lot less attractive: you give back most of the energy you just got from burning the fuel.
5. Suppafly ◴[] No.42127777[source]
They should sell it to people for their car tires with a specially colored valve cap like they do for nitrogen. It'd be stupid, but so is paying extra for a slightly higher nitrogen content and people do that.
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6. jandrese ◴[] No.42127869[source]
That sort of application is just spitting into the ocean when you're talking about global CO2 emissions and sequestration.
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7. criddell ◴[] No.42127874[source]
A tree gives you wood. What are the valuable outputs of grasslands?
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8. Kostic ◴[] No.42127928{3}[source]
Chernozem.
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9. danbruc ◴[] No.42128010[source]
I have not thought about this too carefully so I might be overlooking something. With that out of the way, a quick search indicates that we burn about 90 % of gas, oil, and coal for one purpose or another. Let's round this and pretend we burn it all. To undo this we will essentially need the same amount of energy again that we got out of it when we burned it, we would need to use all the energy coming from fossil fuels to undo burning them. Conservation of energy essentially.

Which makes it obvious that the entire idea is pretty pointless, burn fossil fuels to generate energy to then use it to unburn fossil fuels. To do it with renewable energy, we still need the same capacity as the fossil fuel capacity and when we have that - ignoring issues like fluctuations in renewable sources - it makes more sense to just use the renewable sources directly instead of using them to undo burning fossil fuels.

If you want to use the process to pull carbon out of the atmosphere, then you first have to replace all fossil fuels with renewable ones, then you can use additional renewable capacity to remove carbon. Add additional 10 % capacity to the world energy capacity to undo one year of carbon emissions every decade, at least to a first approximation.

To come back to the initial question, you essentially need an industry the same order of magnitude as the fossil fuel industry to have a meaningful impact. Not going to happen anytime soon.

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10. thechao ◴[] No.42128037{4}[source]
https://en.wikipedia.org/wiki/Chernozem
11. lupusreal ◴[] No.42128074{3}[source]
Does bamboo count?
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12. nostromo ◴[] No.42128078{3}[source]
You can make it into a carbon-neutral heating fuel.

You can make paper products including things like cardboard and packaging.

You can put livestock on it and produce meat.

Or if you just want to sequester carbon, you can harvest it and bury it deep in the ground.

13. sampo ◴[] No.42128082{3}[source]
> What are the valuable outputs of grasslands?

If you use grasslands for grazing cattle you get meat, or also wool with sheep. Sequestering carbon into grassland soil (or into any soil, really) makes them better at absorbing and retaining rainwater, reducing the risks of catastrophic floods in the watershed area.

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14. userabchn ◴[] No.42128093[source]
Have there been any recent developments in "lab-grown wood"? The last time I looked into it there had been some research on it (also at MIT), but there didn't seem to have been any updates for a few years.
15. marcosdumay ◴[] No.42128138[source]
Grass always do it better than trees.

And the GP is quite wrong, because almost everything will be more efficient than trees or grass. Machines are just way more expensive, that's why nobody ever made them.

16. TSiege ◴[] No.42128237[source]
The point that you're missing is that changes this equation a bit is that burning fossil fuels wastes most of the energy as heat another waste of energy is the amount of FFs we use to ship FFs to other places. So together that means we don't need the same amount of electric power to do the same amount of work. That being said, keeping fossil fuels in the ground will always be better than removing CO2 for the reasons you said. We also seem to be growing energy demands instead of shrinking or stabilizing them which also makes the transition harder.
17. axus ◴[] No.42128262[source]
Lots of solar on-site that doesn't need to transfer it's power elsewhere could be used; maybe the real winner would be 100% solar-powered solar panel factory :)
18. newsclues ◴[] No.42128536[source]
What is smarter, spending years researching and arguing the best way to do this, or using the natural process all over, and adapting the best practice locally, to try to solve climate change?

Some places can plant trees, others grasslands. Or whatever, but it seems like there is a lot of money to create an industrial process that can be commercialized instead of just doing the work naturally...

19. criddell ◴[] No.42128563{4}[source]
Maybe. I know it actually is grass, but are bamboo growths called grasslands?
20. criddell ◴[] No.42128565{4}[source]
Good points. I wasn't thinking of second order products.
21. Tyr42 ◴[] No.42128690{3}[source]
Cows?
22. undersuit ◴[] No.42128909{3}[source]
https://en.wikipedia.org/wiki/Cellulose#Commercial_applicati...
23. BenjiWiebe ◴[] No.42128917{3}[source]
Plus it all comes out of the tires in the end anyways.
24. toss1 ◴[] No.42130067[source]
>>we would need to use all the energy coming from fossil fuels to undo burning them

This would true if we need to re-create the original molecule with it's stored energy (plus losses of course).

However, it seems this is a misapprehension of the task. Instead of trying to recover the entire hydrocarbon molecule, we're "just" trying to extract or recombine the CO2 reactant.

Without doing the chemistry or the math, it seems likely that a variety of methods of either preferentially attracting CO2, or combining it into simpler lower-energy-dense molecules to be collected, would require less energy as was in the original hydrocarbon, often substantially less.

Seems it should be an inequality, not an equality. Or am I missing something?

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25. thinkcontext ◴[] No.42130872[source]
> To undo this we will essentially need the same amount of energy again that we got out of it when we burned it

Amine based carbon capture at the smokestack captures about 90% of CO2 with a 20% energy penalty. There's a new natural gas turbine design that captures 100% at no energy penalty (Allam cycle).

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26. r-bryan ◴[] No.42131204[source]
A little stoichometry suggests that, ignoring oxygen, hydrogen, and energy input, the cited worldwide market for C2H4 would be satisfied by just about 1 gigaton of CO2. So if "we need to process gigatons of CO2 annually", that ethylene's gonna pile up.
27. danbruc ◴[] No.42134331{3}[source]
Both those technologies do not undo the burning process, they just capture the carbon dioxide. Like putting a gigantic balloon on top of the smoke stack to trap the flue gases. The real problem here is what do you do with all your captured carbon dioxide? You are producing it at the same rate as you are consuming fossil fuels, for each tanker, pipeline, or train delivering fossil fuels, you will need an equally sized tanker, pipeline, or train transporting the carbon dioxide to some storage facility. For each well or mine extracting fossil fuels you need a equally sized hole in the ground to dump the carbon dioxide into.
28. bryanlarsen ◴[] No.42135702[source]
If you can use the renewable energy directly, that's far better, but often you can't.

Synthetic hydrocarbons let you use renewable energy shifted in time, space, modality or avoid capital costs.

- applications that can't use batteries, like long distance plane flights

- applications where it's cheaper to spend 6X as much for fuel than it is to buy a new vehicle

- for storage more than a few days

etx

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29. danbruc ◴[] No.42137372{3}[source]
Sure, if you capture carbon dioxide from the atmosphere to use it as a storage or transportation medium for renewable energy, that is perfectly fine. Trade some efficiency for overcoming some of the limitations of renewable sources like their variability or the difficulty to store electricity.

But that is not really carbon removal from the atmosphere, you take some out and later put it back. The article however frames the endeavor as removing carbon from the atmosphere, either the one we are currently burning or even the one we burnt in the past. Carbon removal by definition means we can not burn it later somewhere else, we have to permanently store it somewhere. There is no point in turning the carbon into some high quality product if we then just bury it somewhere, you want something cheap to make and easy to store.

As a non-fossile source for chemicals it makes sense but that is just a small fraction of our problem as we just burn most of the stuff.

30. danbruc ◴[] No.42146375{3}[source]
While you are right that capturing the carbon dioxide can be done with relatively little energy, that is not what the article is about. If you capture it, you end up with tons and tons of waste, essentially as much as the fuel you burned, what are you going to do with it? The article is about [...] converting CO2 into useful products [...] so that you do not end up with waste but useful products and the requires as much energy as you got from burning the stuff, at least to a first approximation, you would of course not try to recreate the exact same stuff you just burned.

If you capture the carbon dioxide, then for every supertanker full of oil you burn you need to permanently get rid of a supertanker full of liquid carbon dioxide. This is of course a project of insane scope given that we burn billions of tons every year. So in order to not have to deal with the waste, what if we just turn it into something useful that people will pay for? Because that costs a lot of energy, the energy we just extract. And now you want to put it back in? To get back what you just burned or at least something similar that you could almost certainly produce more efficiently directly from the oil?

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31. toss1 ◴[] No.42147745{4}[source]
OK, yes, building larger-molecule more-useful-stuff will take more energy, and I'll go with the first approximation that it's a similar quantity of energy re-input (some useful things less, some more). And yes, all that product will take substantial volume. Thx for clarifying.

That said, it still seems an extremely useful measure, even if we keep using only single-digit percentages for long-use plastics instead of hydrocarbon fuels.

Let's assume that for the next century or so a bunch of applications will continue to require the convenience and energy-density of liquid hydrocarbons. In order to avoid extracting more and further increasing CO2 levels, we'll have to input significant energy to reconstitute them from CO2. Obviously, inputting that energy from more fossil fuels defeats the purpose, but using renewables will work; and now they are even cheaper energy inputs.

The result would be a cycle of newly fabricated hydrocarbon fuels, which can be custom-optimised for each application. No new CO2 would enter the atmosphere and the existing levels would be reduced by the amount of hydrocarbon fuels (and plastics, etc.) fabricated and in existence throughout the entire chain of existence, fabrication, storage, distribution, transport, in-vehicle, right up to the moment it is burned. With cheaper renewable energy inputs and optimized custom fabrication, it would likely get cheaper than the existing drill/pump/transport/refine process. And, it's permanently sustainable, and as liquid hydrocarbon fuel use declines, custom production can be converted to storable materials.

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32. danbruc ◴[] No.42150878{5}[source]
Totally agree, it makes sense to use renewable sources to produce hydrocarbons from the air, whether to burn them or for chemical products. But to significantly remove carbon from the atmosphere as suggested in the article it makes no sense.