I'm skeptic about psychedelic. Is there enough unbiased research about these stuffs? I myself is interested in it too but so far it is in general illegal in Canada, and I don't consider myself knowledgeable enough to try it out.
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However you said that your not knowledgeable and I guess that you doesn't have access to a milligrams scale, so your better to stay away and learn the theory first. A lot of psilocybin analog (alpha-MethylTryptamine was one of my favorite and it's still available) from Thikal are still legal in Canada so that book is a good place to start learning.