Why would we use lithium ion batteries?
I would imagine the approach to store the energy would be to use the energy from solar panels to do work that can be used to produce electricity later.
For example, you could use solar energy to pump water back uphill to flow down through a hydro electric dam later.
Even if it isn't the most efficient, in the long run it would likely provide the best scalability and least long term environmental impact. Once you have the facility in place, the same water could be pumped uphill to flow back down a million times over with the only overhead replacing water lost through evaporation and maintaining the facility.
Am I missing something that makes such an approach unfeasible?