The problem with taking one step north and leaving the border of Postgres is what you lose, not the direct ops burden.
Postgres land is a comfy place filled with transactions across all your data at once, one backup solution that you (hopefully) have had running for months or years and has been thoroughly tested, and ACID compliance. You have a single host, probably, which means that you are neither Available nor Partion-tolerant, but at least you are Consistent.
The moment you expand beyond a single database host you now have a distributed system, and woe unto you if you don't understand what that means.