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While I agree that nuclear is green, IMO Greenpeace are correct about it not being compatible with the "peace" half: the stuff that makes working reactors is the most difficult part of making a working weapons.
This also means that during the cold war they suspected of being soviet plants.
Those suspicions and yours could both be correct for all I know.
In each case it's pretty obvious. Either they have nuclear weapons that share a supply chain and skills base or there is an existential threat out there.
In Poland's case you can tell when they started seeing an existential threat from when they suddenly got interested in building a plant.