I would happily pay monthly for Firefox - but not to Mozilla Corporation. Will Pay to developers, development support and operations - not to pad the CEO salary.
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Either software developers have to figure out how to out compete the CEO ghouls (without becoming CEO ghouls themselves), or we just have to accept that the CEO ghouls will take their cut. There's no version of this where you can pay for a service, but also dictate how that money is spent.
I'll need to think about this more but one difference that comes to mind after giving it some thought is that donations are a choice. Buying food is not really optional. I'm not going to the store and giving them 50€ because I hope they continue to operate, I give them the money as an equal exchange
There is a group of people who would choose to shop more frequently at a certain place, or tip more, if their favorite place is having trouble, but as far as I know this is only a small effect and market forces decide for 95% whether a place can continue to pay its bills. With open source software development like at Mozilla, barring other income sources, they rely on those 5%. The donators don't need to accept that their money is spent on drugs and mansions¹, the way that they do when buying groceries and the big boss might indeed use the profits in that way
¹ I have no clue what else you would do with the 7M USD a year that someone else quoted. Even at a 50% tax rate (idk what the tax rate is for someone who operates a non-profit in the USA), an average person could literally retire after six months of telling others what to do at this "non profit"