A few years ago I was working at a company that used a robotic arm when an accident occurred. The robot was powered off for maintenance but suddenly turned on, pinned a worker's arm, and threw him against a wall. His arm had numerous fractures and he had severe head injuries but survived.
The other worker in the building was in absolute shambles and couldn't understand what had happened. The CCTV footage was then checked and showed that worker looking at the other while reaching for the power switch and turning on the machine. The switch was not locked out and tagged out, but it was the only switch like it on the whole panel, large and required significant force to turn. No way to accidentally bump it, and the video showed him clearly turning the handle.
He was obviously fired, but no criminal charges were ever brought against him. He had no plausible motive for wanting the other man dead, was severely distraught over the incident. It was simultaneously obvious that he had turned the lever deliberately and had not meant to turn the leaver. A near-lethal combination of muscle memory and a confusion caused the accident. If the lever had been locked and tagged out, that probably would have interrupted his muscle memory and prevented the accident, but it wasn't.
Point is, something can be simultaneously impossible to do inadvertently, but still done mistakenly. A switch designed to never be accidentally bumped, to require specific motions to move it, can still be switched by somebody making a mistake.