Let's say that moving out is not an option :)
E.g. https://www.3m.co.uk/3M/en_GB/p/dc/v000265948
It's snow white out of the box, and after using it for a few hours outside even in relatively clean air, it turns gray (and then dark gray if rubber straps hold for long enough).
The thing with these respirators (and also HEPA filters) is that they become better at filtering out particulates as they get dirtier, not worse; but their resistance to air also grows, so it gets more difficult to breathe over time. The rubber straps usually break before the respirator is very dirty anyway.
Note that these won't do anything against other pollutants (like nitrogen oxides), you need proper gas masks with special filters against those, they cost a lot and only last for a few hours.
That doesn't directly answer your question about urban particulates and PM 2.5, but if you read its specs and it sounds appropriate, I can recommend the product.
[0] https://www.amazon.com/Respirator-replaceable-reusable-filte...
I only use them when the air is really bad.