The octahedron has a much higher angular defect (https://en.wikipedia.org/wiki/Angular_defect) than the dodecahedron, and thus when it is projected onto the sphere the cells are warped a lot. So while their areas may be the same, the shapes vary.
This article explains the geometric construction, and how it leads to the cells being a similar size and shape: https://a5geo.org/docs/technical/platonic-solids
Also from a data visualization point of view, the rectangular cells of Healpix (like S2) are arguably less pleasing to look at than hexagons/pentagons: https://h3geo.org/docs/comparisons/s2#visualization
As a result, when A5 is used as a spatial index, it will generally not have jumps in the cell index values when querying nearby locations on land