I know about the Natufan culture gathering and processing grain with grindstones from about 20k years ago, but don't remember anything from 100k years ago. Were they using grindstones to process grain? I'd have thought grass grains wouldn't be a good food source otherwise.
In any case, the seeming stagnation is part of what I meant by the early part of an exponential curve looking flat: broadly it might look like not much is happening, but there are small changes all the time.
Lack of evidence is also a problem when looking that far back: we have little concrete evidence of what these people were doing with wood, fibres, and other perishable materials.
Having said that, archaeologists used to talk about a "cultural revolution" that happened 20-30k years ago. (Maybe they still talk about it, I just haven't looked at the research recently). This was the period of the famous Lascaux cave paintings and what looks like an explosion of greater complexity in tool assemblages. So it's possible there was some rare cognitive leap at that time, or again it could be that we lack the evidence that would show the more gradual progression.