I played games on a Commodore 64 from cassette tapes, in principal you could record games onto a blank cassette but it was very flaky. Good times though.
I did this all the time... even used a double cassette deck to make copies... azimuth was the problem if the heads were aligned different.. so you used a small screwdriver and the top of the cassette had a small opening, this is where you had to align the heads by listening till it didn't sound distorted.. fun times
From what I remember I had a decent amount of success copying games using a twin tape deck for my amstrad 464. I ended up passing on the amstrad to a colleague over a decade ago, who since moved to the US and is almost certainly on here. If you see this Jim, I found the manual!