When I used XFCE as my daily driver, I once tried installing Chicago95 just for nostalgia and it stick as my daily driver for almost a year! The UI is less distracting than modern UIs and there's something to it that makes it easier to just know which window is open over which window that's lacking in modern UIs (I think it's the over-reliance on soft shadows and the borderless windows).
Eventually, I stopped using it because: 1- it was always annoying to send an screenshot to someone and have to explain that no, I wasn't using Windows 95, and why; 2- the grey-ish look of everything started to bother me over time; 3- I wanted a more integrated desktop experience and moved to KDE Plasma. Still, I configured my Plasma to work like old Windows: window titles on taskbar, zero to none animations, etc.