Eh, it's hardly seamless, and double clicking is extremely uncommon on the web so that would be a big red flag.
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Edit: Actually that's generally I guess triple click. Double to select a word.
Having a mental model of "this button needs to be double clicked" gets them the result they want, even if that's not a very accurate reflection of the computer.
So, the rule:
List of files on your computer or desktop? Double-click. Otherwise? Don't.
In practice: adherence to this ranges from perfect to abysmal. And users who don’t understand the computer well may not know how to think about whether a given UI element is selectable or not.