I don't understand why anyone would use passwordless disk encryption. It just seems inherently vulnerable, especially with the threat model of physical compromise.
Entering a password on boot isn't even that much work
replies(19):
Entering a password on boot isn't even that much work
I believe when using TPM with LUKS the TPM just decrypts the master key and that is handed back to the OS and used in software. So the primary key does end up in RAM.