I built a partial list last year [1]. It's challenging to decide which CAs are government operated or controlled: the names don't always make it clear, private companies may operate under government direction, law may require CAs to follow government requests. These were all very clearly government/military organizations running CAs. The Brazilian CA referenced here is number two on the list.
[1] https://alexsci.com/blog/ca-trust/#government-control-of-cas