I can't claim to be always be good at it, but this is what I strive for as well. I like talking to a candidate about something they are experienced or even expert at, and asking questions until I find the boundary of their ability. It can be very illuminating what happens when they hit it -- some get defensive, some get enthusiastic.
Defensiveness might just mean they're being interviewed and I failed to adequately put them at ease. But usually when we're neck-deep in some specific topic, both of us will kind of forget that it's an interview -- especially since the topic is more in their area of strength than mine.
Otherwise, defensiveness often means they never actually wanted to understand the problem they were working on, they just wanted to use it to get a degree or ship something by throwing it over the wall and forgetting about it. Even someone who is heartily sick of their PhD topic (as in, everyone who is over 1/3 of the way to getting one) will be relieved to discuss the ideas behind it, the reasons why it caught their interest in the first place, when they don't have to do the work of coming up with rigid results and writing them up.
Enthusiasm is usually a good sign, though even there I have to watch out for excessive enthusiasm where they care more about the problem itself than the benefits of solving the problem, and are likely to waste resources in unnecessary pursuits of perfection.
Oh, and finding the limits of someone's knowledge doesn't require a genius, which is fortunate since I am decidedly not one. 3-year olds can do it just by endlessly asking "why?" You'll probably need to be a little more sophisticated than that, which is good since you'll be able to evaluate their ability to explain things to you in the process.
I do like the return key, though.