I would be amazed if there's any even remotely relevant code that deals meaningfully with CHAR_BIT != 8 these days.
(... and yes, it's about time.)
For some DSP-ish sort of processors I think it doesn't make sense to have addressability at char level, and the gates to support it would be better spent on better 16 and 32 bit multipliers. ::shrugs::
I feel kind of ambivalent about the standards proposal. We already have fixed size types. If you want/need an exact type, that already exists. The non-fixed size types set minimums and allow platforms to set larger sizes for performance reasons.
Having no fast 8-bit level access is a perfectly reasonable decision for a small DSP.
Might it be better instead to migrate many users of char to (u)int8_t?
The proposed alternative of CHAR_BIT congruent to 0 mod 8 also sounds pretty reasonable, in that it captures the existing non-8-bit char platforms and also the justification for non-8-bit char platforms (that if you're not doing much string processing but instead doing all math processing, the additional hardware for efficient 8 bit access is a total waste).
This is so old it predates ANSI C; it's in K&R C. It used to show up on various academic sites. Now it's obsolete enough to have scrolled off Google. I've seen copies of this on various academic sites over the years, but it seems to have finally scrolled off.
I think we can dispense with non 8-bit bytes at this point.