I definitely felt Mondays on-call were much busier in the hospital. I always thought this could be due to patients spending weekends with family, not wanting to cause a fuss and maybe ignoring symptoms of cardiac chest pain until it evolves into a serious heart attack (STEMI). Also, they may be waiting to see their GP on Monday morning and then get referred to hospital (although less likely with STEMIs).
I also remember the time between Christmas and New Year being very busy - I thought for a similar reason - people understandably just don't want to be in hospital for Christmas.
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