Part of the "magic" involves finding ratios of elements that have relatively little mechanical strain, because the atoms "fit" just right, which introduce defects that degrade the semiconductor behavior.
Part of the "magic" involves finding ratios of elements that have relatively little mechanical strain, because the atoms "fit" just right, which introduce defects that degrade the semiconductor behavior.
Here's some spectra with 3% FWHM @ 662 keV:
https://maximus.energy/index.php/2020/05/01/gamma-spectrosco...
In semiconductors with indirect band gap, when electron-hole pairs combine they usually just heat the material, instead of emitting light, which is why silicon, for instance, is not suitable for making LEDs.
While a direct band gap is desirable in LEDs, lasers and photodetectors, an indirect band gap is preferable in other applications where you do not want electrons and holes to recombine easily, e.g. in bipolar transistors or SCRs and in many kinds of diodes.
There are plenty of materials that have been known for a long time to be better than those normally used in certain applications, but which still do not replace the inferior alternatives due to excessive cost, so discovering any new process that can make them cheaply is as important as knowing the properties of the material.